AsianScientist (Jul. 19, 2016) – Scientists in Japan have developed a film that curls up and straightens out autonomously when exposed to tiny, barely measurable changes in ambient humidity. When irradiated with ultraviolet light, which causes changes in the film’s ability to absorb and desorb water, it can even ‘jump’ into the air.
Details of the study, carried out by researchers at the RIKEN Center for Emergent Matter Science (CEMS) and the University of Tokyo, were published this week in Nature Materials.
“Our study began from a serendipitous finding. When we placed a compound called guanidinium carbonate into a high-temperature oven, we found that it formed not only a powdery substance—as is usual in similar processes—but also a yellowish film that stuck to the surface of the substrate,” said postdoctoral researcher Dr. Daigo Miyajima of CEMS.
The surprise came when the team began to analyze this unusual film. They were able to remove it from the substrate by soaking it in warm water, and found that it was extremely light despite its toughness.
What they couldn’t explain at first was that at ambient conditions, the material would suddenly bend and then straighten out again, without any obvious external stimulus.
The group carried out a number of experiments to determine why this was happening, and found that the key was tiny, essentially undetectable changes in the ambient humidity. They found, for instance, that moving a drop of water into the vicinity of the film would cause it to straighten, but that this did not happen when they ensured that there was no air motion.
They weighed the film when it was stretched out and curled up, and found a tiny increase of just 680 nanograms per ten square millimeters in the curled-up configuration. They concluded that it was desorbing water on one surface and that the bonds between the water molecules and the polymer created mechanical stress which caused the film to curl up. The change happened extremely rapidly—taking just 50 milliseconds when the film was exposed to ultraviolet light.
The motion was also powerful. When the film was placed on a flat surface and made to curl up, it could literally jump to a height of one centimeter, a height 10,000 times the thickness of the film.
Additionally, the film is durable. In one experiment where the researchers irradiated the film repeatedly with ultraviolet light, it bent and straightened more than 10,000 times without any noticeable deterioration.
In a final experiment, the researchers covered one half of the film with thin gold, to stop the absorption and desorption of water, and then subjected it to repeated curling and straightening. The film could actually walk over a surface, dragging itself as the covered half of the film bent and relaxed.
“In the same way that a mechanical watch takes advantage of the natural movements of the wrist to gain energy, this film takes tiny fluctuations in the ambient humidity and transforms them into mechanical energy,” said Professor Takuzo Aida from the University of Tokyo, a co-corresponding author on the study.
The article can be found at: Arazoe et al. (2016) An Autonomous Actuator Driven by Fluctuations in Ambient Humidity.
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